When switching from iPhone 4S to New iPhone 6 Plus, you must want to transfer all data from iPhone 4S to iPhone 6 Plus. Here is a video guide about copying contacts, messages, video, photos and music from iPhone 4S to iPhone 6 Plus, no need with iTunes.

Watch the guide:
Phone to Phone Transfer for Android, Symbian & iOS
> Transfer various data like contacts, messages, photos, music, videos and apps
> Support Phones from Apple, HTC, Motorola, Nokia, Samsung, Sony, and More
> Work with new Motorola Nexus 6, Samsung Galaxy Note 4, iPhone 6 Plus, etc

 

In fact, iPhone can not transfer data directly to Android. Someone says that we can transfer data from iPhone to android or in turn via email, iCloud, even iTunes. but you must backup data from iPhone via iCloud or email on PC. then transfer them to Android via USB. I provide a way to transfer text messages from iPhone to iPhone, and U can follow to move other files.
1. Set up iCloud both on iPhone and also laptop. Set up the Windows edition if your PC is with Windows OPERATING-SYSTEM.
2. Start the Synchronize feature of the iCloud in the iPhone options.
3. Sign in the iCloud with the Apple ID on the laptop, and you can to control your iPhone data files at this point.
4. Pick the music in your iPhone and synchronize them in your Computer's iCloud, if you like to put them in selected folders, you’re able to down load the music to your local folder.
5. Transfer music which is on PC to Android Phone via USB.

However, the method above is a bit trouble, you can also try some software to transfer data between iPhone and android such as Phone Transfer. that also work well..

 

How to Import iPhone iPad iPod Media? If you want a simple way to copy your data, iPhone Data Transfer is a great solution for you!
iPhone Data Transfer is such an useful data transfer tool that can help you transfer contacts, photos, music, text messages and much more between different Apple devices.
The handy software empowers you to backup photos, SMS, contacts and other files to iTunes or PC in one click.
How to Transfer iPhone SMS to PC
How to Transfer Songs from iPhone to iPad
Easily move playlists from computer/iTunes to iPhone/iPad/iPod touch.
Back up playlists including smart playlists to iTunes.
Okey, all you need is iPhone Data Transfer program to restore everything in your iTunes library with ease.
If you want to have a try, you can follow the steps.
How to Transfer iPod Songs to Computer/iTunes

 

You can use iPhone Transfer to do that. It can connect your two iPhones at the same time and then transfer data for you. You can transfer messages, photos, videos, contacts, calendars, voice memos, ringtones, music, playlists and other data for you. Learn how to transfer music from iPhone to iPhone.