Movies and TV Shows downloaded from iTunes cannot be played on your favorite Android device, what a pity! In fact, the movies and TV Shows purchased/rented from iTunes are under DRM protection which limits users to play them on non-apple devices.

If you want to enjoy iTunes Movies, TV Shows & Music Videos on your android smartphone or tablet, watch and follow this video.
iTunes M4V Converter
> Remove DRM from iTunes M4V movie Rentals & Purchases
> Convert iTunes M4V to plain MP4, MOV, FLV, AVI, MPEG
> Unlock M4V to Android, Windows 8 phones & tablets